Just been looking at doing this myself. From looking at the TreeGroup code, I have managed to get this to work:
local treeStructure = { ... as your post ... }
-- Create tree and set status table.
WidgetTree = AceGUI:Create( "TreeGroup" )
WidgetTree:SetTree( treeStructure )
TreeGroupStatus = { groups = {} }
WidgetTree:SetStatusTable( TreeGroupStatus )
--Tell tree that parent 2 should expand.
TreeGroupStatus.groups[2] = true
-- Refresh tree here.
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In your case, this should make "Enchants" expand.
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http://www.wowace.com/addons/lib-st/
I don't know if it will work with AceGUI-3.0 or not.